刘绍峰博士，教授，博士生导师English

青岛科技大学，高分子科学与工程学院

青岛市郑州路53号，邮编266042

电子邮箱：shaofengliu@qust.edu.cn

教育背景：

2008.10-2011.07 Universite de Strasbourg 博士

2005.09-2011.07 中国科学院化学研究所 博士

2001.09-2005.07 中南大学 学士

工作经历：

2015.01-至今 青岛科技大学 教授，泰山学者青年专家

2011. 07-2014.12 Northwestern University 博士后

2008.07-2008.09 University of East Anglia 访问学者

荣誉称号：

2016年获得泰山学者青年专家称号；

2017年获山东省属优秀青年基金；

2018年获淄博英才计划的支持。

研究领域:

1、聚烯烃金属催化剂开发和高性能聚烯烃材料制备

自上世纪三十年代聚乙烯工业化生产以来，聚烯烃的发展至今已有八十多年的历史；现如今，聚烯烃已是世界上高分子材料中产量最大的产品之一。基于金属催化剂的配位聚合，在聚合物分子量、分子量分布以及聚合物微观结构（端基基团、立体构型、支链、嵌段）等多方面实现可控，大大提高了产品的性能和附加值。该课题拟将金属有机化学、配位化学与高分子化学等多学科有效结合，开发新型聚烯烃金属催化剂--双金属催化剂，利用协同催化效应，以高分子合成为基础，依托化学方法，从分子层面来设计高分子材料的组成和微观结构，制备高性能高附加值聚烯烃材料，如超支化聚烯烃、功能化聚烯烃和嵌段聚烯烃等等。

2、可降解高分子材料—新型催化剂、聚合新方法、聚合物新材料

在从枯竭性资源经济向可再生资源经济转型中，世界各国都非常重视可降解高分子材料的开发和应用，它是新一代的、有发展前景的材料并符合生态和可持续发展的要求。脂肪族聚酯，包括聚乳酸（PLA）、聚己内酯（PCL）、聚乙醇酸（PGA）、聚羟基丁酸酯（PHB）以及聚乙交酯-丙交酯共聚物（PLGA）等，近年来发展迅速，并广泛地应用于组织工程以及缓释、控释和靶向等药物制剂。该课题拟设计新型催化剂，发展新型共聚合反应，开发分子内可逆链穿梭反应等聚合新方法，解决可降解脂肪族聚酯力学性能差、共聚单体选择性差、催化剂的金属利用率低等问题，制备高分子量、高立构规整度、单体组分可控、嵌段等高附加值可降解脂肪族聚酯高分子材料。

3、金属有机化学

合成各种金属有机化合物，并通过NMR、X-ray等研究其结构和性能，并探索它们在不对称催化等中的应用。

代表性论文：

1. Tong Shi, Wenlong Luo, Shaofeng Liu,* and Zhibo Li,* “Controlled random copolymerization of rac-lactide and ɛ-caprolactone by well-designed phenoxyimine Al complexes” J. Polym. Sci., Part A: Polym. Chem. 2018, 56, 611-617.

2. Tong Shi, QuanDe Zheng, WeiWei Zuo, Shaofeng Liu,* and Zhibo Li,* “Bimetallic aluminum complexes supported by bis(salicylaldimine) ligand: Synthesis, characterization and ring-opening polymerization of lactide” Chinese J. Polym. Sci. 2018, 36, 149-156.

3. Huaike Li, Na Zhao, Chuanli Ren, Shaofeng Liu,* and Zhibo Li,* “Synthesis of Linear and Star Poly(ε-caprolactone) with Controlled and High Molecular Weights via Cyclic Trimeric Phosphazene Base Catalyzed Ring-Opening Polymerization” Polym. Chem. 2017, 8, 7369-7374.

4. Shaofeng Liu, Anna M. Invergo, Jennifer P. McInnis, Aidan R. Mouat, Alessandro Motta, Tracy L. Lohr,* Massimiliano Delferro,* and Tobin J. Marks,* “Distinctive Stereochemically Linked Cooperative Effects in Bimetallic Titanium Olefin Polymerization Catalysts” Organometallics 2017, 36, 4403-4421.

5. Na Zhao, Chuanli Ren, Huaike Li, Yunxin Li, Shaofeng Liu,* and Zhibo Li,* “Selective Ring-Opening Polymerization of Non-Strained γ-Butyrolactone Catalyzed by Cyclic Trimeric Phosphazene Base” Angew. Chem., Int. Ed., 2017, 56, 12987-12990.

6. Wenlong Luo, Tong Shi, Shaofeng Liu,* Weiwei Zuo, and Zhibo Li,* “Well-Designed Asymmetric Salphen-Al Complexes: Synthesis, Characterization, and Ring-Opening Polymerization Catalysis” Organometallics, 2017, 36, 1736-1742.

7. Jie Zhang, Shaofeng Liu,* Weiwei Zuo, Hongqi Ye,* and Zhibo Li, “Synthesis of Dinuclear Aluminum Complexes Bearing Bis-phenolate Ligand and Application in Ring-opening Polymerization of ε-Caprolactone” New J. Chem., 2017, 41, 2358-2363.

8. Shaofeng Liu,* Jie Zhang, Weiwei Zuo, Wenjuan Zhang, Wen-Hua Sun,* Hongqi Ye and Zhibo Li, “Synthesis of Aluminum Complexes Bearing 8-Anilide-5,6,7-trihydroquinoline Ligands: Highly Active Catalyst Precursors for Ring-Opening Polymerization of Cyclic Esters” Polymers, 2017, 9, 83.

9. Wenlong Luo, Antai Li, Shaofeng Liu,* Hongqi Ye, and Zhibo Li, “2‑Benzimidazol-6-pyrazol-pyridine Chromium(III) Trichlorides: Synthesis, Characterization, and Application for Ethylene Oligomerization and Polymerization” Organometallics, 2016, 35, 3045-3050.

10. Jie Zhang, Shaofeng Liu*, Antai Li, Hongqi Ye*, and Zhibo Li, “Nickel(ii) complexes chelated by 2,6-pyridinedicarboxamide: syntheses, characterization, and ethylene oligomerization” New J. Chem., 2016, 40, 7027-7033.

11. Shaofeng Liu, Alessandro Motta, Aidan R. Mouat, Massimiliano Delferro,* and Tobin J. Marks,* “Very Large Cooperative Effects in Heterobimetallic Titanium-Chromium Catalysts for Ethylene Polymerization/Copolymerization” J. Am. Chem. Soc., 2014, 136, 10460-10469.

12. Shaofeng Liu, Alessandro Motta, Massimiliano Delferro,* and Tobin J. Marks,* “Synthesis, Characterization, and Heterobimetallic Cooperation in a Titanium-Chromium Catalyst for Highly Branched Polyethylenes” J. Am. Chem. Soc., 2013, 135, 8830-8833.

13. Shaofeng Liu, Roberto Pattacini, and Pierre Braunstein,* “Reactions between an ethylene oligomerization Cr(III) pre-catalyst and Al-based activators: alkyl and cationic complexes with a tridentate N,P,N ligand” Organometallics, 2011, 30, 3549-3558.

14. Shaofeng Liu, Wen-Hua Sun,* Yanning Zeng, Deligeer Wang, Wenjuan Zhang, and Yan Li, “Syntheses, Characterization, and Ethylene (Co-)Polymerization Screening of Amidate Half-titanocene Dichlorides” Organometallics, 2010, 29, 2459-2464.

15. Shaofeng Liu, Riccardo Peloso, and Pierre Braunstein,* “Palladium and iridium complexes with a N,P,N-bis(pyridine)phenylphosphine ligand” Dalton Trans., 2010, 39, 2563-2572.

16. Shaofeng Liu, Riccardo Peloso, Roberto Pattacini and Pierre Braunstein,* “Electrophilic activation and the formation of an unusual Tl⁺/Cr³⁺ tetranuclear ion-complex adduct” Dalton Trans., 2010, 39, 7881-7883.

17. Shaofeng Liu, Jianjun Yi, Weiwei Zuo, Kefeng Wang, Deligeer Wang, and Wen-Hua Sun,* “N-(2-Benzimidazolylquinolin-8-yl)benzamidate Half-Titanocene Chlorides: Synthesis Characterization and Their Catalytic Behavior towards Ethylene Polymerization” J. Polym. Sci., Part A: Polym. Chem., 2009, 47, 3154-3169.

18. Shaofeng Liu, Weiwei Zuo, Shu Zhang, Peng Hao, Deligeer Wang, and Wen-Hua Sun,* “Bis(2-(6-methylpyridin-2-yl)-benzimidazolyl)titanium dichloride and Titanium Bis(6-benzimidazolylpyridine-2-carboxylimidate): Synthesis Characterization and Their Catalytic Behaviors for Ethylene Polymerization” J. Polym. Sci., Part A: Polym. Chem., 2008, 46, 3411-3423.